Api rp 571, damage mechanisms affecting fixed equipment in the refining industry, third edition, is a recommended practice developed and published by the american petroleum institute api that provides an indepth look at over 60 different damage mechanisms. As with other cracking mechanisms, there is a threshold stress level where cracking will not occur. Similarly other specific stress corrosion cracking processes have acquired their own names. Stress corrosion cracking international institute of. Avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments synopsis this maintenance best practice guide is concerned with the performance of carbon and low alloy steels, and austenitic stainless steels, in chloride and caustic. Risk of stress corrosion cracking attack caustic stress corrosion cracking occurs at higher temperatures than chloride stress corrosion cracking which can occur at temperatures as low as 60 degc. Mechanisms of stress corrosion cracking and intergranular attack in alloy 600 in high temperature caustic. For cscc to cause a failure, a number of factors and conditions must. Stress corrosion cracking behavior of nickel base alloys.
Specialized corrosion doehdbk1015193 corrosion ch02 rev. Stress corrosion cracking scc hydrogen damage sulphur corrosion graphitization thermal fatigue waterside corrosion fatigue soot. Corrosion, stress corrosion cracking, and electrochemistry of. Sodium hydroxide solutions are used in a variety of. An experimental program on stress corrosion cracking scc aimed at the development of a quantitative model for predicting the behavior of inconel 600 tubing in high temperature water is currently underway at brookhaven national laboratory bnl. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc.
Caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at. Im hoping to add to the contributions in this field of research by taking the time to archive notable events in my lab. Although stress corrosion cracking of duplex stainless steels in chloride solution has been investigated and well documented in the literature but the scc mechanisms for dss in caustic solutions were not known. Stress corrosion cracking scc is the formation and growth of crack through materials subjected to tensile stress and a specific corrosive medium. Stress corrosion cracking susceptibility of medium carbon steel in caustic and potash media a. Austenitic stainless steels suffer from scc in chlorides, caustic, and. Evidence of intergranular attack iga in the absence of stress, together with dissolution kinetics, indicates that intergranular stress corrosion cracking igscc of ferritic steels in various environments is by a dissolution mechanism. The paper discusses stress corrosion cracking scc of stainless steel components due to the ingress of caustic into steam systems. Caustic scc is driven by tensile stress, susceptible material and concentration of caustic.
Industrial experience on the caustic cracking of stainless. Borode school of chemical and metallurgical engineering, faculty of engineering and the built. Carbon steel in caustic service corrosion engineering. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Learn vocabulary, terms, and more with flashcards, games, and other study tools. Due to power ated within these limits, no major stress ful concentrating mechanisms operative in corrosion cracking. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms. Effect of temperature and some inhibitors on stress corrosion. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. The design engineer may not always be fully aware of lhe possibility of brittle failures in fastener systems that could result from stress corrosion cracking scc or hydrogen stress cracking hsc. Stress corrosion cracking caustic embrittlement of super. These alloys can however suffer from caustic stress corrosion cracking at caustic concentrations above 70% at temperatures above 290crmo c 550f.
Caustic stress corrosion cracking inspectioneering. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Caustic embrittlement focuses on the stressed parts of the boiler, including cracks, bends, rivets and joints. For caustic stress corrosion cracking, what is the effect of temperature and concentration mechanisms.
Potentiostatically controlled tests were conducted near the activepassive transition, using fracture mechanics testing techniques and fatigue precracked double cantilever beam specimens. The mechanism of stress corrosion cracking is not well understood but it is believed to be caused by stress, corrosive environments and susceptible microstructures. Caustic stress corrosion cracking caustic embrittlement. Michael j schofield bsc, msc, phd, mim, ceng, in plant engineers reference book second edition, 2002.
Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment it is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. The design of industrial structures and components is usually based on tensile. Metalenvironment combinations susceptible to cracking are specific. Three basic mechanisms of stress corrosion cracking have been identified as.
The five categories of stainless steels and key features essential for stress corrosion cracking are introduced. Caustic stress corrosion cracking creative engineers, inc. The mechanism of scc is shown as a simple representation in figure 1. Explains caustic embrittlement, season cracking, hydrogen.
The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. In an ideal world a stress corrosion cracking control strategy will start operating at the design stage, and will focus on the. Stress corrosion cracking of carbon steel in caustic. These alloys can however suffer from caustic stress corrosion cracking at caustic. Avoiding stress corrosion cracking of carbon low alloy and. Caustic embrittlement is also known as stress corrosion cracking. It becomes increasingly more corrosive with increasing temperature and concentration. Selection of stainless steels for handling sodium hydroxide. Stress corrosion cracking of inconel alloy 600 in high. The most damaging forms of stress corrosion cracking in austenitic stainless steels are chloride and caustic stress corrosion cracking and cracking in high temperature, high pressure aqueous environments. This due to high concentration of the caustic soda added to the boiler water to control ph ph 9. So, lack of pwht will increase susceptibility, mostly from residual tensile stresses, and not just hardness.
Schematic view of stress corrosion cracking scc and corrosion fatigue cracking. Microstructural changes during fabrication processes affect the overall scc susceptibility of these steels in caustic. Caustic embrittlement was first used to describe the cracking of riveted mild steel boiler plates due to local deposition of concentrated hydroxide at temperatures of 200 to 250 o c 400 to 480 o f. Stress corrosion cracking of stainless steel components in.
Cracking mechanism an overview sciencedirect topics. Biological corrosion, bacterial corrosion, microbial corrosion. The impact of scc on a material usually falls between dry cracking and. Scc is well known as the major mechanism of alloy 600 sg tubing failure occurring in the. Consequently, caustic corrosion called caustic embrittlement more accurately, a specific kind of stress corrosion cracking was engendered on the carbon steel tubes under both concentrated naoh and tensile stress because the operational pressure of the tube side was larger than the shell side, and corrosion products including na 3 feo 3, na. In order to have scc, three conditions must be satisfied. The model is based on the idea of a straininduced rupture of the protective film, and so plastic strains play a main role in failure processes 52, 55. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. Real components will typically contain defects and design.
This due to high concentration of the caustic soda added. Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc. Results confirmed that the chromate ions act as an oxidizing inhibitor and prevent caustic cracking. Stress corrosion cracking behavior of alloy 600 coupled to.
The lead author outlined in the first half of the paper that during scheduled outages on two power generating units at his company, nondestructive testing ndt revealed stress corrosion cracking. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. External chloride stress corrosion cracking ecscc is a specific form of cui that occurs in austenitic stainless steels 300 series ss. Stress corrosion cracking scc of type 316 stainless. Caustic corrosion an overview sciencedirect topics. Environmental cracking season cracking caustic cracking caustic embrittlement stress corrosion cracking scc hydrogeninduced. Most of those who own solid stainless steel equipment operating in the cui temperature range are likely to experience ecscc at some point. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially. Stainless steels are more resistant to general corrosion compared with carbon steel.
Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Austenitic stainless steels are better at resisting. Caustic stress corrosion cracking cscc is a failure mechanism affecting both the carbon and austenitic stainless steels. This mechanism has been extensively studied in stress corrosion cracking of alpha brass in ammoniacal environment and also proposed for caustic cracking of boiler steel. Although amines form a high ph solution and may cause scc, it is considered a different mechanism for the purposes of this standard and amine scc is not addressed. As with other forms of stress corrosion cracking, caustic cracking will. The mechanism is similar to that of chloride stress corrosion.
Also, the fracturemechanics con cept of design assumes preexisting flaws in materials, although these may not be surface flaws that can become stress corrosion. Stress corrosion cracking of inconel alloy 600 in high temperature wateran update. This explains the stress corrosion and the conditions. Mechanisms and modeling of stress corrosion cracking in.
The impact of scc on a material usually falls between dry cracking. Tube od surfaces experience thermal fatigue stress cycles which can occur from normal shedding of slag, sootblowing, or from cyclic operation of the boiler. Introduction in the united states currently there are approximately 104 operating light water reactors. It was later known as stress corrosion cracking which is in turn replaced by caustic cracking. Cracking mechanisms in which corrosion is implicated include stress corrosion cracking, corrosion fatigue, hydrogeninduced cracking and liquid metal embrittlement. Consequently, caustic corrosion called caustic embrittlement more accurately, a specific kind of stress corrosion cracking was engendered on the carbon steel tubes under both concentrated naoh and tensile stress because the operational pressure of the tube side was larger than the shell side, and corrosion. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Three different mechanisms involved in stress corrosion. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Stress corrosion cracking scc of type 304 stainless steel in 20n caustic solution was investigated in the presence of chromate ions, using the constant strain rate 10sup 710sup 5s technique. Protecting your steam turbine from corrosion power. Feb 22, 2001 chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Corrosion of this type generally results from fouled heat transfer surfaces and the presence of an active corrodent sodium hydroxide in the boiler water6,7.
Although fatigue is a degradation mechanism that is second in importance to radiation. French metallurgists news letter page 1 of 7 stress corrosion cracking scc is a welldefined failure mechanism in metals. Caustic corrosion caustic corrosion is referred to as caustic attack, caustic gouging, or ductile gouging. Nace sp0403 avoiding caustic stress corrosion cracking. In some cases crack initiation has been associated with the formation of a brittle film at the surface of the material, which could have lower ductility due to a different metal.
Stresscorrosioncracking view from the penthouse the. Thermal cycling, in addition to subjecting the material to cyclic stress, can initiate cracking of the less elastic external tube scales and expose the tube base material to repeated corrosion. Intergranular stress corrosion cracking weld decay knifeline attack kla exfoliation layer corrosion stray current corrosion. Then, the stress corrosion cracking mechanism for various materials in. Alloy 400 n04400 and alloy 600 n06600 also have excellent stress corrosion resistance. On the other hand, polyesters are readily degraded by acids, and scc is a likely failure mechanism. Aug 01, 2018 caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to. Stress corrosion cracking, a very important topic of machine design.
Introduction in the united states currently there are approximately 104 operating. There is caustic stress corrosion cracking when carbon steel is exposed to concentrated caustic solution. Corrosionpedia what is stress corrosion cracking scc. Crack propagation can increase dramatically with temperature and can grow through the wall in a matter of hours during temperature excursions especially in conditions that promote caustic concentration. Caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. Careful design and operation of caustic injection equipment is needed to. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Also, the fracturemechanics con cept of design assumes preexisting flaws in materials, although these may not be surface flaws that can become stresscorrosion. Environmental cracking season cracking caustic cracking caustic embrittlement stress. May 09, 2009 part 2 flow accelerated corrosion fac. In practice, most cases have been attributed to caustic cracking and extreme care. Api rp 571 damage mechanisms affecting fixed equipment.
Crack propagation can increase dramatically with temperature and can grow through the wall in a matter of hours during temperature excursions especially in conditions that promote caustic. Stresscorrosioncracking view from the penthouse the dnfm. Residual sodium carbonate, which is used for the softening process, undergoes hydrolysis, forming sodium hydroxide at high pressures and temperatures. Chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Stress corrosion cracking and hydrogen embrittlement of. Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620 o c to 705 o c, depending upon prior solution treating temperature. Despite the extensive qualification of inconel for specific applications, a number of corrosion problems have arisen with inconel tubing. It can lead to unexpected sudden failure of normally ductile metals. The area of risk in sodium hydroxide is shown on the iso corrosion diagram by the area bounded by a green line. May 06, 2014 stress corrosion cracking, a very important topic of machine design.
Carbon steel in caustic service corrosion engineering eng. For cscc to cause a failure, a number of factors and conditions must be present in the correct amounts. Stress corrosion cracking of duplex stainless steels in. Susceptibility to caustic scc is dependent on several variables, including alloy content, caustic concentration, temperature and stress level.
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